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41.
北方陆相二叠系—三叠系界线研究是界线地层研究的重要问题之一,对采自内蒙古巴林右旗幸福之路组二段建组剖面的安山质岩屑晶屑凝灰岩开展锆石LA-ICP-MS U-Pb测年,结果为(255.5±1.1)Ma,火山岩上部多个层位粉砂质泥岩中发现孢粉化石,计17属20种,时代为晚二叠世—早三叠世,推断幸福之路组的时代为晚二叠世—早三叠世,大兴安岭地区二叠系—三叠系界线在幸福之路组内部,二者为整合接触。幸福之路组以红层做为划分标志,岩性为正常沉积碎屑岩夹火山岩,见大量泥灰岩夹层、钙质结核及干裂现象,反映了炎热、干燥及强氧化条件的气候环境,大兴安岭地区晚二叠世晚期(幸福之路组二段下部)就已出现反映干旱气候的红层沉积,与相邻的华北及新疆准噶尔盆地相似。  相似文献   
42.
钽矿是我国的紧缺资源,近年来对别也萨麻斯地区钽矿取得了找矿新进展,包括新矿点的发现以及花岗伟晶岩型稀有金属资源的找矿突破。区内伟晶岩脉广泛发育,为探究含矿脉体的成矿时代、查明区内典型铌钽矿物的矿物学特征,本文以L18号伟晶岩脉中的钽锰矿为研究对象,对其物理性质、化学成分、地质年代等进行了分析。应用电子探针测试钽锰矿的化学组成,热电离质谱法(TIMS)测定其U-Pb年龄,确定含矿脉体的形成年代。结果表明,研究区钽锰矿中Ta_2O_5含量为51.58%~74.80%,均值68.49%,Nb_2O_5含量为6.15%~27.63%;部分主量元素分布不均,未表现出规律的分带性,但矿物颗粒中心部位的CaO含量较边部低,横剖面上SiO_2含量相对稳定,TiO_2与WO_3显示不规律波动。这种特征表明钽锰矿并非单纯由结晶分异作用形成,而是可能受到了后期交代作用的影响。钽锰矿的U-Pb年龄为160Ma,说明钽锰矿化发生于晚侏罗世早期,与围岩海西期二云母花岗岩相差甚远,后者并非L18号脉体的成矿母岩。  相似文献   
43.
榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5~37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(~35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8~-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。  相似文献   
44.
The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle.  相似文献   
45.
46.
In the northwestern sector of the Zagros foreland basin, axial fluvial systems initially delivered fine-grained sediments from northwestern source regions into a contiguous basin, and later transverse fluvial systems delivered coarse-grained sediments from northeastern sources into a structurally partitioned basin by fold-thrust deformation. Here we integrate sedimentologic, stratigraphic, palaeomagnetic and geochronologic data from the northwestern Zagros foreland basin to define the Neogene history of deposition and sediment routing in response to progressive advance of the Zagros fold-thrust belt. This study constrains the depositional environments, timing of deposition and provenance of nonmarine clastic deposits of the Injana (Upper Fars), Mukdadiya (Lower Bakhtiari) and Bai-Hasan (Upper Bakhtiari) Formations in the Kurdistan region of Iraq. Sediments of the Injana Formation (~12.4–7.75 Ma) were transported axially (orogen-parallel) from northwest to southeast by meandering and low-sinuosity channel belt system. In contrast, during deposition of the Mukdadiya Formation (~7.75–5 Ma), sediments were delivered transversely (orogen-perpendicular) from northeast to southwest by braided and low-sinuosity channel belt system in distributive fluvial megafans. By ~5 Ma, the northwestern Zagros foreland basin became partitioned by growth of the Mountain Front Flexure and considerable gravel was introduced in localized alluvial fans derived from growing topographic highs. Foredeep accumulation rates during deposition of the Injana, Mukdadiya and Bai-Hasan Formations averaged 350, 400 and 600 m/Myr respectively, suggesting accelerated accommodation generation in a rapidly subsiding basin governed by flexural subsidence. Detrital zircon U-Pb age spectra show that in addition to sources of Mesozoic-Cenozoic cover strata, the Injana Formation was derived chiefly from Palaeozoic-Precambrian (including Carboniferous and latest Neoproterozoic) strata in an axial position to the northwest, likely from the Bitlis-Puturge Massif and broader Eastern Anatolia. In contrast, the Mukdadiya and Bai-Hasan Formations yield distinctive Palaeogene U-Pb age peaks, particularly in the southeastern sector of the study region, consistent with transverse delivery from the arc-related terranes of the Walash and Naopurdan volcano-sedimentary groups (Gaveh-Rud domain?) and Urumieh-Dokhtar magmatic arc to the northeast. These temporal and spatial variations in stratigraphic framework, depositional environments, sediment routing and compositional provenance reveal a major drainage reorganization during Neogene shortening in the Zagros fold-thrust belt. Whereas axial fluvial systems initially dominated the foreland basin during early orogenesis in the Kurdistan region of Iraq, transverse fluvial systems were subsequently established and delivered major sediment volumes to the foreland as a consequence of the abrupt deformation advance and associated topographic growth in the Zagros.  相似文献   
47.
在野外地质调查和室内综合研究的基础上,通过对黄梅尖地区辉绿玢岩K-Ar年代学、地球化学和Sr-Nd同位素特征进行研究,探讨辉绿玢岩的形成时代、岩石成因及构造背景。K-Ar年代学研究表明,辉绿玢岩形成于~107 Ma,是早白垩世岩浆活动的产物,形成时代晚于该地区火山岩和侵入岩,与该地区铀成矿年龄基本一致;辉绿玢岩的侵入可能是该地区岩浆作用的最后一幕,铀成矿可能与辉绿玢岩具有成因联系。地球化学特征表明,辉绿玢岩富集大离子亲石元素K、Rb、U、Pb和轻稀土元素,亏损高场强元素Nb、Ta、P、Ti,具有较高的Isr值和负εNd(t)值,具有富集地幔源区特征;辉绿玢岩是在地壳伸展和岩石圈减薄的构造背景下,由俯冲交代作用形成的富集地幔部分熔融形成的,表明~107 Ma时该地区仍处于伸展构造环境下。  相似文献   
48.
Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ18O value was determined by CO2 laser fluorination (δ18OLF). GRS2 has δ18OLF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ18OLF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ18OLF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.  相似文献   
49.
Plutonic rocks from the Mineiro Belt, Brazil record a delayed onset of the transition from TTG to sanukitoid-type magmatism(high Ba-Sr), starting during the Siderian magmatic lull when little juvenile magma was added to the continental crust. Rocks mostly belong to the calc-alkaline series, meta-to peraluminous and originally "Ⅰ-type",meaning that oxidized magmas were formed by partial melting of subducted material. The temporal distribution and apparent secular changes of the magmas are consistent with the onset of subduction-driven plate tectonics due to an increase of the subduction angle and opening of the mantle wedge. New isotopic analyses(Sm-Nd whole rock and Lu-Hf in zircon)corroborate the restricted juvenile nature of the Mineiro Belt and confirm the genetic link between the Lagoa Dourada Suite,a rare ca. 2350 Ma high-Al tonalite-trondhjemite magmatic event, and the sanukitoid-type ca. 2130 Ma Alto Maranhao Suite. U-Pb dating of zircon and titanite constrain the crystallisation history of plutonic bodies; coupled with major and trace element analyses of the host rocks, they distinguish evolutionary trends in the Mineiro Belt. Several plutons in the region have ages close to 2130 Ma but are distinguished by the lower concentration of compatible elements in the juvenile high Ba-Sr suite.  相似文献   
50.
Despite the recent development in radiometric dating of numerous zircons by LA-ICPMS, mineral separation still remains a major obstacle, particularly in the search for the oldest material on Earth. To improve the efficiency in zircon separation by an order of magnitude, we have designed/developed a new machine-an automatic zircon separator(AZS). This is designed particularly for automatic pick-up of100 μm-sized zircon grains out of a heavy mineral fraction after conventional separation procedures. The AZS operates in three modes:(1) image processing to choose targeted individual zircon grains out of all heavy minerals spread on a tray,(2) automatic capturing of the individual zircon grains with microtweezers, and(3) placing them one-by-one in a coordinated alignment on a receiving tray. The automatic capturing was designed/created for continuous mineral selecting without human presence for many hours. This software also enables the registration of each separated zircon grain for dating, by recording digital photo-image, optical(color) indices, and coordinates on a receiving tray. We developed two new approaches for the dating; i.e.(1) direct dating of zircons selected by LA-ICPMS without conventional resin-mounting/polishing,(2) high speed U-Pb dating, combined with conventional sample preparation procedures using the new equipment with multiple-ion counting detectors(LA-MIC-ICPMS).With the first approach, Pb-Pb ages obtained from the surface of a mineral were crosschecked with the interior of the same grain after resin-mounting/polishing. With the second approach, the amount of time required for dating one zircon grain is ca. 20 s, and a sample throughput of 150 grains per hour can be achieved with sufficient precision(ca. 0.5%).We tested the practical efficiency of the AZS, by analyzing an Archean Jack Hills conglomerate in Western Australia with the known oldest(4.3 Ga) zircon on Earth. Preliminary results are positive; we were able to obtain more than 194 zircons that are over 4.0 Ga out of ca. 3800 checked grains, and 9 grains were over 4300 Ma with the oldest at 4371 ± 7 Ma. This separation system by AZS, combined with the new approaches, guarantees much higher yield in the hunt for old zircons.  相似文献   
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